Why not? By the time I got into networking I'd moved on to Windows 95, GNU/Linux, and Samba. Up until this point, I had zero experience with using Windows for Workgroups as a client. Hell, when I actually used Windows 3, it was never even attached to a network.
I set up Windows 2000 Server as an AD server for my other retro machines, along with KiX scripts and roaming profiles et al. Whilst in the process of joining 9x and NT-based clients to the domain, I wondered to myself "should I do this with Windows for Workgroups too?"
Well, duh… of course I should!